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๐Ÿš€ Thermodynamics is the branch of physics that deals with the relationships between heat, work, and internal energy. In thermodynamics, heat is understood as a form of energy transfer that occurs due to a temperature difference between systems. This concept is crucial for understanding how energy is conserved and transformed in physical processes. The first law of thermodynamics states that the change in internal energy of a system is equal to the heat added to the system minus the work done by the system on its surroundings. This relationship helps us analyze various thermodynamic processes and understand how energy flows in different forms.

Theory Explanation

Understanding Heat Transfer

Heat is energy that is transferred from one body to another due to a temperature difference. It can flow from a hotter object to a cooler one until thermal equilibrium is reached. This transfer can occur through conduction, convection, or radiation.

Work Done by a System

Work is defined as the energy transferred when a force is applied to an object over a distance. In thermodynamics, work can be done by a system (expansion work) or on a system (compression work). The work done by a gas during expansion can be calculated using the formula W = Pฮ”V, where P is the pressure and ฮ”V is the change in volume.

\[ W = P \Delta V \]
Internal Energy

Internal energy (U) is the total energy contained within a system, including kinetic and potential energy at the molecular level. The change in internal energy can be expressed as ฮ”U = Q - W, where Q is the heat added to the system and W is the work done by the system.

\[ \Delta U = Q - W \]

Key Points

  • ๐ŸŽฏ Heat is energy transfer due to temperature difference.
  • ๐ŸŽฏ Work is energy transfer due to force applied over a distance.
  • ๐ŸŽฏ Internal energy is the total energy within a system.
  • ๐ŸŽฏ The first law of thermodynamics relates heat, work, and internal energy.
  • ๐ŸŽฏ Understanding these concepts is essential for analyzing thermodynamic processes.

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Examples:💡

A gas in a piston expands from a volume of 2.0 L to 5.0 L against a constant pressure of 1.0 atm. Calculate the work done by the gas during this expansion.

Solution:

Step 1: Identify the initial and final volumes and the pressure. Initial volume (V1) = 2.0 L, Final volume (V2) = 5.0 L, Pressure (P) = 1.0 atm.

Step 2: Calculate the change in volume: ฮ”V = V2 - V1 = 5.0 L - 2.0 L = 3.0 L.

\[ \Delta V = V_2 - V_1 = 5.0 \text{ L} - 2.0 \text{ L} = 3.0 \text{ L}. \]

Step 3: Convert the pressure from atm to Joules: 1 atm = 101.3 J/L. Therefore, P = 1.0 atm = 101.3 J/L.

Step 4: Calculate the work done using the formula W = Pฮ”V: W = 101.3 J/L * 3.0 L = 303.9 J.

\[ W = P \Delta V = 101.3 \text{ J/L} \times 3.0 \text{ L} = 303.9 \text{ J}. \]

Common Mistakes

  • Mistake: Confusing heat with temperature. Heat is energy transfer, while temperature is a measure of thermal energy.

    Correction: Remember that heat is the energy that flows due to a temperature difference, while temperature is a measure of how hot or cold an object is.

  • Mistake: Forgetting to convert units when calculating work or heat.

    Correction: Always check that your units are consistent, especially when using formulas that involve pressure, volume, and energy.

  • Mistake: Misapplying the first law of thermodynamics by not correctly identifying heat and work contributions.

    Correction: Carefully analyze the system to determine what heat is added and what work is done, ensuring you apply the correct signs in the equation ฮ”U = Q - W.